Hideki Motosuwa
Hideki Motosuwa is a 19-year-old repeat studentattempting to get into university by studying at Seki cram school, which his parents have sent him to. They have also severed his allowance, which means he has to work at Yorokonde (My Pleasure), an izakaya, to make ends meet. One night, while walking home from work, he finds a persocom lying in a pile of garbage. He takes her home, and after much searching, switches her on and finds that the only word she can utter is "Chi". Because of this, he gives her the name "Chi" and takes her into his care, doing his best to protect and teach her.

Chi
Chi is a "chobit," a technologically advanced persocom rumored to possess true sapience, unlike other persocoms.She is found by Hideki one night in a pile of trash as he makes his way home from work. Upon turning her on, she is only able to say the word "chi," remembers nothing of her past life, and is unable to perform even simple tasks. Because of this, Hideki names her Chi and undertakes teaching her how to function. Because her system cannot be scanned by other persocoms, Minoru Kokubunji suggests she may be one of the legendary chobits. Minoru tells Hideki that Chi needs software to perform common persocom functions such as email, but that he doesn't know which ones and to wait for Chi to tell you herself.
Chitose Hibiya
Chitose Hibiya s the landlady at the apartment where Hideki is staying. In the manga, she was previously an employee of Piffle Princess Enterprises and participated in the development of Angels and later, persocoms. She was married to the president of the company, the late Ichiro "Icchan" Mihara, who used the data gathered from the Angelic Layer research to create the Chobits to be Chitose's children, because she was unable to have children of her own. She also authors the A City with No People series of books to help Chi find the Person Just for Her.Hiromu Shinbo
Hiromu Shinbo is Hideki's best friend and is also studying at Seki cram school. In the anime, Shinbo lives in the same apartment complex as Hideki and is his next-door neighbor. Shinbo is usually the first person Hideki turns to for help with persocoms. Shortly after beginning school he becomes romantically involved with his teacher Takako Shimizu, after finding her in a park late at night because she had been unwittingly locked out of her house by her husband, who was too busy with his persocom. He later elopes with her and convinces her to marry him.
Sumomo
Sumomo is a miniature "mobile persocom"—the equivalent of a laptop computer. Wearing an outfit that makes her resemble a genie, she is programmed to be cute and tends to be quite hyperactive, for example leading Hideki in wakeup exercises each morning and dancing when she is in standby mode. Shinbo was the original owner of Sumomo, but left her with Hideki after leaving with Takako. He later transfers Sumomo's registration to Hideki, giving him permanent ownership. At the beginning of the series, Shinbo uses Sumomo in an attempt to analyze Chi, and Sumomo is nearly broken in the process, requiring new main memory, and in the manga, a new video card as well. Once Kotoko joined Hideki, she quickly came to the conclusion that Sumomo was mad, with her nonsensical ways.Minoru Kokubunji
Minoru Kokubunji is a wealthy twelve-year old genius, whose specialty is persocoms. In particular, he has built a custom persocom named Yuzuki, designed to look like his late sister, and has given her self-teaching software, meaning that she can learn things on her own instead of having to have programs loaded into her as is the case with most persocoms.For the most part, Minoru is a very reserved and soft spoken individual who surrounds himself with persocoms. His curiosity over Chi's origins leads to him becoming one of Hideki Motosuwa's closest friends.Yuzuki
Yuzuki is a persocom created by Minoru Kokubunji roughly two years before the start of the series. Yuzuki was created to resemble, physically and mentally, Minoru's late sister, Kaede, who had died from an illness two years earlier. Yuzuki is programmed with all of the data that Minoru could remember about his sister; what she liked, what she disliked, as well as her habits and behaviors. However, Minoru still realizes that no matter how realistic she may be, she is still only a persocom that is following her programming. Yuzuki also possesses an awareness of her own limitations.Freya
Freya was the first Chobit, who was created before Elda by Hibiya's husband, Ichiro Mihara. Freya was created to be Hibiya's daughter, because she was unable to bear children of her own. Freya's development was kept secret from Hibiya; she did not know of Freya's existence until she was called down to the lab one day, without explanation. Upon awakening for the very first time, she was given the name Freya by Hibiya.In the anime, Freya never found the courage to tell her father how she truly felt; in the manga, she resigns herself to the fact that because of the damage to her body, all hope is lost regardless of the outcome, and chooses to tell him her true feelings.
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